Initial stages of stress corrosion cracking in austenitic. Transgranular stress corrosion cracking of 304l stainless. Stainless steel pipe pipe and tube products arch city steel. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. A high chlorine peak was observed in both locations indicating high chloride levels. Higher levels of chloride might cause crevice corrosion and pitting. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Stress corrosion cracking facts and how to reduce the risk. Loto department of chemical and metallurgical engineering, tshwane university of technology, pretoria, south africa received dec 2012, revised 1 feb 20, accepted 1 feb 20 email address. Outside diameter initiated stress corrosion cracking.
Come to us for your 304304l304h stainless steel pipe alloy 304l is a low carbon austenitic stainless steel. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. Subject to pitting and crevice corrosion in warm chloride environments, and to stress corrosion cracking above about 60c. Pdf the stress corrosion cracking of austenitic stainless steel. Stress corrosion cracking in a brewery paul mueller company. It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. Direct use geothermal heating relies on heat extracted from naturally occurring geothermal water sources to provide heating needs for commercial and residential use. Chloride stress corrosion cracking inspectioneering. Type 304 stainless steel showed extensive tgscc in solution annealed condition in 144 h exposure tests. For this reason, many products have dual certification as 304304l and 304. The reasons of the leakage for austenitic stainless steel tubes and overlay welding layer on the tube. All three families of the highperformance stainless steels will deliver a wide range of resistance to chloride pitting and stress corrosion cracking superior to that of types 304 and 316.
Scc occurred due to high stresses imparted during pipe and elbow fabrication alexander et al. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. Effects of marine environments on stress corrosion cracking. Earlier duplex alloys have had moderate resistance to general corrosion and chloride stress corrosion cracking, but suffered a substantial loss of properties when used in the aswelded condition. Our rich inventory includes an extensive list of stainless steel products like stainless steel pipe and fittings, tubes, flanges, bar stocks, sheets, plates and hollow bars. Corrosion of this type has been extensively studied and affects almost all metal alloys, including the austenitic grades of stainless steel used in brewing. Ammonium hydroxide stainless steela ahow good resistance to all concentrations of ammonia. Stress corrosion cracking is a localised mechanism of corrosion that requires a tensile stress, a susceptible material and a specific environment. In fresh waters of up to mgl chloride content, type 316 is. Stress cracking can be minimized by annealing the metal, after manufacture to remove residual manufactured stresses. The sensitized structure is an indication of the materials susceptibility to intergranular corrosion andor cracking.
The alloys 304, 304l, and 304h are the most susceptible of the austenitic stainless steels to stress corrosion cracking scc in halides because of their relatively low nickel content. While the surveyed studies all explore scc of austenitic stainless steels under atmospheric conditions, the. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Boiling magnesium chloride test thirtysix type 304 stainless steel elbows from four different fabricators were tested in boiling magnesium chloride solution. With stainless steel it takes the form of pitting, crevice corrosion and stress corrosion cracking scc. High performance stainless steels nickel institute. Scc is a form of corrosion that occurs in nearly all alloys, including the grades of stainless steel commonly used in brewery equipment types 304, 304l, 316, and 316l.
Stress corrosion cracking revised final white paper cc. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. While type 304 sensitized stainless steel suffer intergranular attack and scc in the. Stress corrosion cracking of type 304 stainless steel. The chloride ion cl is the most common of these and is found in everyday materials such as salt and bleach. A precursor of stress corrosion cracking in chloride bearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting.
Pitting corrosion is avoided by making sure that stainless steel does not come into prolonged contact with harmful chemicals or by. Austenitic stainless steel may be susceptible to chloride stress corrosion cracking cscc. Corrosion resistance of stainless steel tubes seawater. Chloride corrosion of carbon steel pipe engineering. Type 304 stainless steel an overview sciencedirect topics. Pdf chloride induced stress corrosion cracking of type 304 and. Scc will occur when stainless steels are subjected to tensile stress, while in contact with solutions containing chlorides.
Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. As the name implies, localized corrosion affects only specific local areas rather than the broad surface of the metal. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Cl and s elements were detected in corrosion products from the corrosion pits and the cracks by eds. What is the maximum chloride in ppm that can be allowed in.
Carbon steel and type 304 stainless steel samples were exposed in thirteen corrosion tests conducted in solutions with varying ph, oxygen content, so 2 content and chloride ion content in a simulated sour water solution produced in the laboratory. Pitting corrosion evaluation of austenitic stainless steel type 304 in acid chloride media r. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and. Considered resistant to potable water with up to about 200mgl chlorides at ambient temperatures, reducing to about 150mgl at 60c. The standard 304304l and 316316l grades are most susceptible. Stress corrosion cracking scc 316l pipe fitting with stress corrosion cracking. Mar 21, 2018 today we will combine practical cases to analyze the most common corrosion types of stainless steel. The resistance of types 304 and 316 stainless steels to. The influence of chloride concentration and acidity on the occurrence of stress corrosion cracking s. High residual or applied stress, temperature above 6571c 150160f and chlorides increase the likelihood of cscc. Stainless steel gains its ability to resist corrosion by forming a passive layer on its surface. There can be a risk of stress corrosion cracking scc attack at higher temperatures, which is common to both the 304 and. Preventing stress corrosion cracking of austenitic stainless steels in chemical plants. Trace levels of chlorides were detected on the fracture surface by.
If you you have temperatures above 150f,you could have stress corrosion cracking of 316 although unlikely below 200 f. Ctlstress corrosion cracking of a stainless steel pipeline. Residual stresses can arise from welding, common in the piping system, or. Pitting corrosion evaluation of austenitic stainless steel. A macro of the exterior surface and a crosssection of the pipe illustrate typical stress corrosion cracking. Stress corrosion cracking of sensitized type 304 stainless. Pdf chloride stress corrosion cracking scc of type 304 and.
Figure 1 shows the cracking that occurred on a 6mo super austenitic stainless steel n08367 exposed to 0. Effect of halogens and inhibitors on the external stress. Chloride stress corrosion cracking and 316 stainless steel. Subject to pitting and crevice corrosion in warm chloride environments, and to stress corrosion cracking above about 600c. Failure of the tube was due to chloride stress corrosion cracking. If this is a potable water as described,there is no reason to consider anything but carbon or galvanized steel. Stress corrosion cracking scc is a common issue with many specialty alloys. Stainless steels are more resistant to general corrosion compared with carbon steel. Chloride stress corrosion cracking of buried stainless steel. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e.
Increasing nickel content above 18 to 20% or the use of duplex, or ferritic stainless steels improves resistance to cscc. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Common corrosion forms of stainless steel you should know. Chlorides are present in a wide variety of industrial environments kolotyrkin. Chloride stress corrosion cracking in austenitic stainless steel. The primary concern in this case is for an insidious form of corrosion called chloride stress corrosion cracking, which gives little indication of crack initiation in very low halide levels, and in the. Austenitic steels of type astm 304 and 316 austenitic steels have limited. Type 304304l stainless steel with exposure to up to. Corrosion resistance stress corrosion cracking 2205 is a cost effective solution for many applications where 300 series stainless steels are susceptible to chloride stress corrosion cracking scc. Pitting corrosion the passive layer on stainless steel can be attacked by certain chemical species. Odscc of stainless steel piping represents an immediate safety concern. Reference is often made to stainless steel in the singular sense as if it were one material. Below 80 degc they can be considered resistant to any concentration of sodium hydroxide, up to the limit of solubility.
Through controlled addition of nitrogen to alloy 304, 304l can meet the same mechanical properties as 304. Zhu, stress corrosion cracking of type 304 stainless steel weldments in the active state, corrosion. What forms of corrosion can occur in stainless steels. Occasionally, conditions are encountered that cause localized attack, usually crevice corrosion, of these alloys. Methods of minimizing chloride stress corrosion cracking. Stress corrosion cracking scc of austenitic stainless steels has been a known failure mode for more. I can only relate what i know about the specific corrosion of type 304 stainless steel used for valve pipe fittings in the nuclear pwr industry. Modes such as pitting, crevice, stress corrosion cracking, sulfide stress corrosion cracking, integranular, galvanic, contact, passivation and pickling are covered. Stress corrosion cracking of type aisi 304 stainless steel at. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Three general classifications are used to identify stainless steels. What is temperature it is more important than concentration of chloride and anything higher than room temperature higher is worse. Chloride corrosion of carbon steel pipe engineering stack.
Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of. Therefore, the scc concerns for spent fuel storage canisters identified in a november 2004 presentation by nuclear and. Stress corrosion cracking of a 304 stainless steel elbow. Chloride stress corrosion cracking in austenitic stainless. Summary of available data for estimating chlorideinduced scc. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media.
Failure of stainless steel 304l air cooler tubes due to stress. What are the effects of chlorides and fluorides on 316. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Corrosion resistance chloride stress cracking ak steel nitronic 19d stainless steel, like other duplex stainless steels, offers superior chloride stress corrosion cracking resistance relative to fully austenitic stainless steels like types 304 and 316. The methodology of the drip procedure of the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to the insulation industry. Chloride induced stress corrosion cracking of type 304 and. Both 304 and 316 stainless steel types are resistant to a wide range of concentration and temperature. Stainless steels are corrosionresistant, but to take full. During stage 2, electrochemical activity combined with the applied stress effect the cracking behavior of the normally ductile 304 stainless steel and colonies of short, brittle, transgranular cracks initiate fig. Boiling magnesium chloride induces cracking in stainless steel under tensile stress and was employed as a chemical cracking test to characterize residual stresses. The strain associated with the formation and opening of these cracks provides some stress relief resulting in a crack.
To evaluate chlorideinduced stress corrosion cracking of type 304 stainless steel, corrosion 2012, march 1115, 2012, salt lake city, ut, agencywide documents access and management system adams accession no. Scc propagation rates for atmospheric corrosion of 304ss. Chloride stress corrosion cracking and 316 stainless steel moltenmetal chemical 20 jul 11 07. Guidelines for using stainless steel in the water and. This level of chloride is considered to be the limit for the 188 alloys, particularly if crevices are present.
The typical crack morphology for chloride stress corrosion cracking consists of branched transgranular cracks. Design guidelines for the selection and use of stainless steel nidl distributed by. Excellent in a wide range of atmospheric environments and many corrosive media. Corrosion rates were calculated, and ubends were examined for stresscorrosion cracking. Stress corrosion cracking is a general term describing stressed alloy failures appearing as cracks in the stainless steel that occur in corrosive environments. Stress corrosion cracking by cooling water of stainless steel shell and tube. As its name suggests, scc takes the form of a network of cracks that eventually will lead to sudden, catastrophic failure in your tanks. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion.
A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Chloridechlorine levels and stainless steel alloy selection. Stainless steel pipe pipe and tube products arch city. Table 8 chloride stress cracking resistance alloy hours to failure. The nitrogen serves to significantly improve the corrosion resistance of the alloy. If the cl is present as hcl you have a problem that 316 wont solve. Energy dispersive spectroscopy eds was used to analyze the surface scale and crack surface. Integral to johns manville thermo1200 and to sproule wr1200 is xox corrosion inhibitor, a distinctive formula and process that inhibits corrosion to the outside surfaces of pipe and equipment, especially stress corrosion cracking.
Effects of marine environments on stress corrosion. Type 304 stainless steel is highly susceptible to scc in chloride solution as demonstrated by the results of exposure of constant strain samples kain 1997, kain et al. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. The 304 and 304l 188 stainless steel alloys have been utilized very successfully in fresh waters containing low levels of chloride ion of up to 100 ppm. The elbow was welded with two straight pipes at two ends. If it is necessary to insulate stainless steel pipe a special chloride free insulation can be purchased or the pipe can be coated with a protective film prior to insulating.
The cracks had initiated intergranularly before changing to a transgranular mode of crack propagation, typical of stress corrosion cracking of austenitic stainless steels in chloride environments. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of. Today we will combine practical cases to analyze the most common corrosion types of stainless steel. Chlorideinduced transgranular stress corrosion cracking of. The 150 to 260 ppm levels found in the soil beside the pipeline are sufficient. Types 304 and 316 stainless steel are widely and successfully utilized in piping and equipment to handle fresh waters. Stainless steel gains its ability to resist corrosion by. Jan 08, 2002 while stainless steels are often used for their corrosion resistance, they do in fact suffer from corrosion under certain circumstances. The source of chloride was the organic chlorides present in the process stream. Ctlchloride stress corrosion cracking of buried stainless. Carbon steel and ferritic stainless steels, with little to no nickel, do not experience cl scc, nor do high nickel alloys those with ni over 30% are much less prone. Resistance to chloride stress corrosion cracking is correlated with nickel content, with the 25% nickel ss 904l alloy, showing improved resistance compared to an 8% nickel alloy like type 304 stainless steel.
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